Suppression of Schlenk Equilibration and Heavier Alkaline Earth Alkyl Catalysis: A Dearomatization Strategy
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Suppression_of_Schlenk_Equilibration_and_Heavier_Alkaline_Earth_Alkyl_Catalysis_A_Dearomatization_Strategy/2677168
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Reaction of a bis(imino)acenapthene with the heavier alkaline earth dialkyls [Ae{CH(SiMe3)2}2(THF)2] (Ae = Mg, Ca, Sr) results in deromatization of the aromatic ligand and the isolation of heteroleptic alkyl species which show unprecedented stability toward Schlenk-type redistribution and exceptional catalytic activity toward the hydroamination of aminoalkenes.
创建时间：
2016-02-23
