Preparation and Characterization of a Halogen-Bonded Shape-Persistent Chiral Alleno-acetylenic Inclusion Complex
收藏Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Preparation_and_Characterization_of_a_Halogen_Bonded_Shape_Persistent_Chiral_Alleno_acetylenic_Inclusion_Complex/2321326
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A chiral bidentate inclusion complex has been formed by halogen-bond interaction between the pyridyl moieties of a pyridoallenoacetylenic host and octafluorodiiodobutane. X-ray crystallography showed that the guest adopts a chiral conformation inside the molecular channels formed by stacking of the host units. A 10 ppm shielding of the 15N NMR resonance for the pyridil units provided evidence of the formation of the halogen-bond complex in solution.
创建时间：
2016-02-18
