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Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

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https://figshare.com/articles/dataset/Stepwise_Reduction_of_Dinitrogen_Bond_Order_by_a_Low-Coordinate_Iron_Complex/3637848 数据链接链接失效反馈

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Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

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创建时间：

2016-08-18

氮气活化

催化剂设计

Understanding the interaction of N2 with iron is relevant to the iron catalyst used in the Haber process and to possible roles of the FeMoco active site of nitrogenase. The work reported here uses syn

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Electron-Deficient Iron Alkyl Complexes Supported by Diimine Ligand (Ph 2 CN) 2 C 2 H 4 : Evidence for Reversible Ethylene Binding

乙烯可逆结合

铁配合物催化

Reaction of diimine ligands (Ph2CN)2CnH2n (n = 2, a; n = 3, b) with FeCl2 or FeBr2 results in formation of the corresponding high-spin ferrous complexes {(Ph2CN)2C2H4}FeX2 (1a, X = Cl; 2a, X = Br) and

NIAID Data Ecosystem30

Catalytic Silylation of Dinitrogen by a Family of Triiron Complexes

氮氧化物催化

铁配合物催化

A series of triiron complexes supported by a tris(β-diketiminate)cyclophane (L3–) catalyze the reduction of dinitrogen to tris(trimethylsilyl)amine using KC8 and Me3SiCl. Employing Fe3Br3L affords

NIAID Data Ecosystem20

Nitrogen Atom Transfer from a Dinitrogen-Derived Vanadium Nitride Complex to Carbon Monoxide and Isocyanide

氮气活化

碳氮键构建

Reduction of [(ONO)V(THF)] with KH under an N2 atmosphere cleaves the NN bond to afford a bis(μ-nitride) V(IV) dimer. This complex is oxidized to generate a V(V) nitride. The reactions of the V

NIAID Data Ecosystem50

A Five-Coordinate Phosphino/Acetate Iron(II) Scaffold That Binds N 2 , N 2 H 2 , N 2 H 4 , and NH 3 in the Sixth Site

氮气活化

酶模拟化学

A family of iron(II) complexes that coordinate dinitrogen, diazene, hydrazine, and ammonia are presented. This series of complexes is unusual in that the complexes within it feature a common auxiliary

NIAID Data Ecosystem20

Stepwise Reduction of Dinitrogen Bond Order by a Low-Coordinate Iron Complex

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