Materials Data on SmSiOs2C by Materials Project
收藏Mendeley Data2024-01-31 更新2024-06-28 收录
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https://www.osti.gov/servlets/purl/1722701/
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SmOs2SiC crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Sm3+ is bonded in a distorted rectangular see-saw-like geometry to four equivalent C4- atoms. All Sm–C bond lengths are 2.71 Å. Os+1.50- is bonded in a 1-coordinate geometry to three equivalent Si4+ and one C4- atom. All Os–Si bond lengths are 2.50 Å. The Os–C bond length is 1.89 Å. Si4+ is bonded in a 6-coordinate geometry to six equivalent Os+1.50- atoms. C4- is bonded to four equivalent Sm3+ and two equivalent Os+1.50- atoms to form a mixture of edge and corner-sharing CSm4Os2 octahedra. The corner-sharing octahedral tilt angles are 22°.
创建时间:
2024-01-31



