Dithiolato-Bridged Dinuclear Iron−Nickel Complexes [Fe(CO)<sub>2</sub>(CN)<sub>2</sub>(μ-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S)Ni(S<sub>2</sub>CNR<sub>2</sub>)]<sup>-</sup> Modeling the Active Site of [NiFe] Hydrogenase
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[NiFe] hydrogenase, the enzyme of which catalyzes the reversible oxidation of molecular hydrogen to protons and electrons, contains a unique heterodinuclear thiolate-bridged Ni−Fe complex in which the iron center is coordinated by CO and CN. We have synthesized dithiolate-bridged Ni−Fe complexes bearing CO and CN ligands to model the active center of [NiFe] hydrogenase. The Ni−Fe complexes containing a [(CN)2(CO)2Fe(μ-S2)NiS2] framework are the closest yet structural models of [NiFe] hydrogenase.
创建时间：
2016-05-12
