Total Synthesis of (±)-Sculponeatin N
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https://figshare.com/articles/dataset/Total_Synthesis_of_Sculponeatin_N/2336620
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资源简介:
The
first total synthesis of the (±)-sculponeatin N (a 6,7-seco-ent-kaurane diterpenoid discovered
by Sun and co-workers) has been achieved. The features include a regio-
and stereoselective aldol reaction to form a lactone, an intramolecular
Diels–Alder reaction to install B and C rings simultaneously,
and a radical cyclization to forge the D ring.
创建时间:
2016-02-18



