Aza-BODIPY Route to Ageladine A
收藏Figshare2022-02-07 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Aza-BODIPY_Route_to_Ageladine_A/19131443
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资源简介：
The marine natural product ageladine A was synthesized by exploiting novel aza-BODIPY-type boron complexes that allowed the regioselective dibromination of the pyrrole unit, as confirmed by quantum chemical calculation (ωB97XD/TApr-cc-pVDZ). The parent tricycle was accessed by Suzuki–Miyaura cross-coupling employing Buchwald’s precatalyst. The boron complex of ageladine A exhibited strong fluorescence that was greater than that of the natural product by a factor of ∼30 and that disappeared in the presence of 2-azido groups.
创建时间：
2022-02-07
