Reversible Repositioning of Zinc Atoms within Single Crystals of a Zinc Polycarboxylate with an Open-Framework Structure
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Upon dehydration at 220 °C under vacuum, an open-framework zinc tetrahydrofuran-2,3,4,5-tetracarboxylate undergoes reversible single crystal to single crystal conversion by some of the zinc atoms moving to different positions that are 3 Å away. The reverse process occurs at room temperature by exposing dehydrated crystals to air.
创建时间：
2004-09-01
