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Versatile Coordination Mode of LiNaB8O13 and α- and β‑LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

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Figshare2016-02-12 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Versatile_Coordination_Mode_of_LiNaB_sub_8_sub_O_sub_13_sub_and_and_LiKB_sub_8_sub_O_sub_13_sub_via_the_Flexible_Assembly_of_Four_Connected_B_sub_5_sub_O_sub_10_sub_and_B_sub_3_sub_O_sub_7_sub_Groups/2086702
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Three new alkali-metal mixed borates, LiNaB8O13, α-LiKB8O13, and β-LiKB8O13, containing a 3∞[B8O13] three-dimensional network have been successfully synthesized. Their fundamental building block is [B8O16]8– formed by the vertex-sharing [B5O10]5– and [B3O7]5– groups, which are topologically identical when they are considered as four-connected nodes. The viewpoints give us a feasible way to investigate the versatile structure assembly of borates with a complex network.
创建时间:
2016-02-12
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