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First Magnetostructural Study on a Heterodinuclear 2,2′-Bipyrimidine-Bridged Complex

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https://figshare.com/articles/dataset/First_Magnetostructural_Study_on_a_Heterodinuclear_2_2_Bipyrimidine_Bridged_Complex/2570266
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The use of the [ReCl4(bpym)] precursor as a ligand toward the fully solvated nickel­(II) metal ion affords the first example of a 2,2′-bipyrimidine-bridged ReIV–NiII complex, [ReCl4(μ-bpym)­NiBr2(H2O)2] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.
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2011-12-19
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