Donor-acceptor complex formation by social self-sorting of polycyclic aromatic hydrocarbons and perylene bisimides
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Additional data to report https://doi.org/10.1039/D3CC03704E Self-assembly versus complexation with polycyclic aromatic hydrocarbon (PAH) guest molecules is studied for a series of perylene bisimides (PBIs). Bulky imide substituents at the PBI guide their self-assembly into dimer aggregates with null-type exciton coupling. Host-guest titration experiments with perylene and triphenylene PAHs afford 1:1 and 1:2 complexes whose properties are studied by single crystal X-ray analysis and UV/Vis and fluorescence spectroscopy.
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2023-09-11
