Selective Derivatization of a Hexaphosphane from Functionalization of White Phosphorus
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https://figshare.com/articles/dataset/Selective_Derivatization_of_a_Hexaphosphane_from_Functionalization_of_White_Phosphorus/5464021
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资源简介：
The
reaction of LGa (L = Dipp(4-(Dipp-imino)pent-2-en-2-yl)amide; Dipp:
2,6-diisopropylphenyl) and white phosphorus was revisited. A plethora
of unprecedented polyphosphanes in addition to the known monoinserted
product LGaP4 (1) are observed. An optimized
synthesis of the hitherto unknown hexaphosphane (LGa)2P6 (3) is presented, and its subsequent selective
derivatization with Brønsted acids, MeOTf, Ph2ECl
(E = P, As), and NaOCP provides access to a wealth of functionalized
hexa- and heptaphosphanes.
创建时间：
2017-10-03
