P(NMe2)3‑Mediated Aziridination of Imines with α‑Ketoesters for Synthesis of Aziridine-2-carboxylates
收藏Figshare2016-12-21 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/P_NMe_sub_2_sub_sub_3_sub_Mediated_Aziridination_of_Imines_with_Ketoesters_for_Synthesis_of_Aziridine-2-carboxylates/4488068
下载链接
链接失效反馈官方服务：
资源简介：
Aziridination of N-sulfonyl imines with α-ketoesters in the presence of P(NMe2)3 is reported. Adducts derived from trivalent phosphorus reagents and α-ketoesters are effectively intercepted by imines, affording a range of aziridine-2-carboxylates. The diastereoselectivity of the reaction depends on steric hindrance from substituents on the substrates.
创建时间：
2016-12-21
