Influence of functionalized substituents on the light-induced electron-transfer abilities of entatic copper guanidinequinoline complexes
收藏ESRF Portal2027-01-01 更新2026-04-23 收录
下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-1730951894
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资源简介：
The fundamental scientific question, addressed in the current proposal is the interplay between structural and electronic degrees of freedom, their constraints and their role in improving electron transfer (ET) properties in Cu complexes. We aim at disentangling structural and electronic effects by studying model complexes with dominating influence of one or the other type of modification. Even though the changes of different nature are applied, they lead to a similar improvement in ET abilities compared to the unmodified complex. Unique capability of ID09 beamline to combine structurally sensitive Wide-angle X-ray scattering (WAXS) and electronically sensitive X-ray emission spectroscopy (XES) will allow separating and resolving the effects of structural and electronic constraints.
提供机构：
Universitaet Hamburg,Center for Free-Electron Laser Science,Luruper Chaussee 149,22761 HAMBURG,GERMANY,22761,HAMBURG,GERMANY; RWTH Aachen University,Institut fuer Anorganische Chemie,Landoltweg 1,52074 AACHEN,GERMANY,52074 ,AACHEN,GERMANY; European XFEL,Femtosecond X-Ray Experiments Group,Holzkoppel 4,22869 HAMBURG,GERMANY,22869,HAMBURG,GERMANY; European XFEL,Scientific Instrument FXE,Holzkoppel 4,22869 SCHENEFELD,GERMANY,22869,SCHENEFELD,GERMANY
创建时间：
2027-01-01
