Selective Catalytic Synthesis of Unsymmetrical Ethers from the Dehydrative Etherification of Two Different Alcohols
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下载链接:
https://figshare.com/articles/dataset/Selective_Catalytic_Synthesis_of_Unsymmetrical_Ethers_from_the_Dehydrative_Etherification_of_Two_Different_Alcohols/2237494
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资源简介:
The cationic ruthenium–hydride
complex [(C6H6)(PCy3)(CO)RuH]+BF4– catalyzes selective etherification
of two different alcohols to
form unsymmetrically substituted ethers. The catalytic method exhibits
a broad substrate scope while tolerating a range of heteroatom functional
groups in forming unsymmetrical ethers, and it is successfully used
to directly synthesize a number of highly functionalized chiral nonracemic
ethers.
创建时间:
2016-02-16



