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Molecular Structure in the Solid State of Bis(pentamethylcyclopentadienyl)germanium

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https://figshare.com/articles/dataset/Molecular_Structure_in_the_Solid_State_of_Bis_pentamethylcyclopentadienyl_germanium/3226102
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Decamethylgermanocene GeCp*2 (1) (Cp* = Me5C5) was synthesized starting from a solution of GeBr and was obtained as colorless crystals. The molecular structure of 1 was determined by X-ray diffraction, showing that 1 is monomeric in the solid state, featuring two pentahapto-bonded Cp* ligands in a bent configuration with a bending angle of 162°.
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2016-05-05
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