Synthesis and Pd-catalyzed coupling of1-C-stannylated glycals
收藏Figshare2019-01-07 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_and_Pd-catalyzed_coupling_of1-_i_C_i_-stannylated_glycals/7073144
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1-Tributylstannyl glycals were applied as versatile tools in the Pd(0)-mediated synthesis of glycal phthalonitrile conjugates. Likewise, selective homo-coupling of 1-tributylstannyl glycals furnishing C1-C1’ linked glycal dimers was investigated by using Pd(II)-species. For both Stille type couplings the rate-accelerating effect of copper(I) thiophene-2-carboxylate (CuTC) was exploited. The synthesis of stannylated glycal precursors was significantly improved by establishing a one-pot two-step procedure via glycosyl sulfoxides.
创建时间：
2019-01-07
