Role of ionization energy on mixed conduction in polythiophene-derived polyelectrolyte complexes

Conjugated polyelectrolyte complexes formed by the electrostatic compatibilization between a conjugated and an insulating polyelectrolyte are a versatile design platform for highly processable, high-performing polymeric mixed ion−electron conductors. While electrostatic mediation in complexes allows for structure and property control, a fundamental understanding of how the properties of the constituent conjugated polyelectrolyte (CPE) translate to the resulting complex performance is necessary for future designs. To investigate the role of CPE architecture on the overall charge transport properties of the resulting complex properties, here we compare a water-soluble cationic poly(alkoxythiophene) derivative based on poly(3-alkoxy-4-methylthiophene) with an imidazolium pendant unit and bromide counterion to an analogous complex with poly(sodium 4-styrenesulfonate). Through spectroscopic, morphological, electrochemical, and charge transport characterization, we find that poly(alkoxythioph..., , This README.txt file was generated on 2025-06-20 by PRATYUSHA DAS

GENERAL INFORMATION

1. Title of Dataset: Role of Ionization Energy on Mixed Conduction in Polythiophene-Derived Polyelectrolyte Complexes
2. Author Information
A. Principal Investigator Contact Information
Name: Rachel A. Segalman
Institution: University of California, Santa Barbara
Address: Materials Research Laboratory, University of California, Santa Barbara, California 93106
Email: [[e-mail]](mailto:[e-mail])

B. Principal Investigator Contact Information
Name: Michael L. Chabinyc
Institution: University of California, Santa Barbara
Address: Materials Research Laboratory, University of California, Santa Barbara, California 93106
Email: [[e-mail]](mailto:[e-mail])

C. Associate or Co-investigator Contact Information
Name: Pratyusha Das
Institution: University of California, Santa Barbara
Address: Materials Research...,