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Phosphine-Catalyzed Sequential [2 +3] and [3 + 2] Annulation Domino Reaction of γ‑Benzyl-Substituted Allenoates with α,β-Unsaturated Ketimines To Construct aza-Bicyclo[3,3,0]octane Derivatives

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NIAID Data Ecosystem2026-03-08 收录
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https://figshare.com/articles/dataset/Phosphine_Catalyzed_Sequential_2_3_and_3_2_Annulation_Domino_Reaction_of_Benzyl_Substituted_Allenoates_with_Unsaturated_Ketimines_To_Construct_aza_Bicyclo_3_3_0_octane_Derivatives/2324815
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资源简介:
A novel phosphine-catalyzed sequential [2 + 3] and [3 + 2] annulation domino reaction of γ-benzyl-substituted allenoates has been developed. The reaction can proceed smoothly to produce the corresponding aza-bicyclo­[3,3,0]­octane derivatives in good yields and excellent diastereoselectivity (only one isomer).
创建时间:
2016-02-18
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