Dataset for: Thermodynamic and Spectroscopic Identification of Methane Inclusion in the Binary Heterocyclic Compound Hydrates

This dataset reports Raman spectroscopy data for methane and aromatic ring compounds (pyridine, pyrrole). The data show that methane and aromatic ring compounds occupy small and large cavities of structure II hydrates. Micro-differential scanning calorimetry (Micro-DSCII, SETARAM) data is included that shows the role of aromatic compounds in the binary clathrate hydrate.本数据集收录了甲烷与芳香环类化合物（吡啶(pyridine)、吡咯(pyrrole)）的拉曼光谱数据。数据表明，甲烷与该类芳香环化合物分别占据II型结构水合物的小空腔与大空腔。数据集同时包含微量差示扫描量热法（Micro-differential scanning calorimetry, Micro-DSCII，SETARAM）数据，用以阐释芳香类化合物在二元笼型水合物中的作用。