The Diastereoselective Alkylation of Arenesulfenate Anions Using Homochiral Electrophiles
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A series of Boc-protected β-amino sulfoxides were prepared by the reaction of arenesulfenate anions with chiral Boc-protected β-amino iodides. The stereoselective substitution reaction is believed to arise through precoordination of the sulfenate counterion with the nitrogen lone pair of the electrophile.
创建时间：
2016-02-23
