Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release
收藏Figshare2019-10-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Copper_I_Complex_Mediated_Nitric_Oxide_Reductive_Coupling_Ligand_Hydrogen_Bonding_Derived_Proton_Transfer_Promotes_N_sub_2_sub_O_sub_g_sub_Release/10072559
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资源简介：
A cuprous chelate bearing a secondary sphere hydrogen bonding functionality, [(PV-tmpa)CuI]+, transforms •NO(g) to N2O(g) in high-yields in methanol. Ligand derived proton transfer facilitates N–O bond cleavage of a putative hyponitrite intermediate releasing N2O(g), underscoring the crucial balance between H-bonding capabilities and acidities in (bio)chemical •NO(g) coupling systems.
创建时间：
2019-10-17
