An OCO3– Trianionic Pincer Tungsten(VI) Alkylidyne: Rational Design of a Highly Active Alkyne Polymerization Catalyst
收藏Figshare2016-02-21 更新2026-04-29 收录
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https://figshare.com/articles/dataset/An_OCO_sup_3_sup_Trianionic_Pincer_Tungsten_VI_Alkylidyne_Rational_Design_of_a_Highly_Active_Alkyne_Polymerization_Catalyst/2540536
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资源简介：
Synthesis, characterization, and catalytic alkyne polymerization results for the first trianionic pincer alkylidyne complex, [tBuOCO]WCC(CH3)3(THF)2 (6), are described. Complex 6 is a highly active catalyst for the polymerization of acetylenes and exhibits a high turnover number (4371), activity (1.05 × 106 gPPA molcat–1 h–1), and yield (87%) for the polymerization of 1-ethynyl-4-fluorobenzene.
创建时间：
2016-02-21
