Photoredox-Catalyzed Tandem Cyclization of Enaminones with N‑Sulfonylaminopyridinium Salts toward the Synthesis of 3‑Sulfonaminated Chromones

A photoredox-catalyzed intermolecular tandem sulfonamination/cyclization of enaminones was realized by using N-aminopyridinium salts as the sulfonaminated reagents without transition-metal catalysts or bases. The reaction exhibits a broad scope and good functional group tolerance, good yields, and regioselectivity. Preliminary mechanistic studies support the radical property of the reaction and the involvement of N-centered radical intermediates.