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Planar Chiral Tetrasubstituted [2.2]Paracyclophane: Optical Resolution and Functionalization

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https://figshare.com/articles/dataset/Planar_Chiral_Tetrasubstituted_2_2_Paracyclophane_Optical_Resolution_and_Functionalization/2318176
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资源简介:
We achieved optical resolution of 4,7,12,15-tetrasubstituted [2.2]­paracyclophane and subsequent transformation to planar chiral building blocks. An optically active propeller-shaped macrocyclic compound containing a planar chiral cyclophane core was synthesized, showing excellent chiroptical properties such as high fluorescence quantum efficiency and a large circularly polarized luminescence dissymmetry factor.
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2014-03-05
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