Accessing Benzimidazoles via a Ring Distortion Strategy: An Oxone Mediated Tandem Reaction of 2‑Aminobenzylamines
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https://figshare.com/articles/dataset/Accessing_Benzimidazoles_via_a_Ring_Distortion_Strategy_An_Oxone_Mediated_Tandem_Reaction_of_2_Aminobenzylamines/3457703
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An exceptional oxone mediated tandem transformation of 2-aminobenzylamines to 2-substituted benzimidazoles is reported. It occurs at room temperature with aromatic, heteroaromatic, and aliphatic aldehydes. In this reaction initial condensation of 2-aminobenzylamine with appropriate aldehydes afforded a tetrahydroquinazoline intermediate which underwent oxone-mediated ring distortion to afford the desired compounds in moderate to excellent yields.
创建时间：
2016-06-27
