Substituent-Dependent, Switchable Synthesis of Nonaromatic and Aromatic Heterocyclic Sulfones Using Visible Light

In this Letter, we described a visible-light-induced switchable synthesis of nonaromatic and aromatic sulfonyl heterocycles. The product selectivity between 2,5-dihydropyrrole and pyrrole can be tuned by altering the substituent on the N atom of 1,6-diyne. We highlight the intricacy and efficiency of this approach in constructing molecular frameworks under mild conditions with a high functional group tolerance. This study elucidates the mechanism underlying product selectivity, highlighting its potential as a compelling alternative to traditional synthetic techniques.