Dimercuration of Calix[4]arenes: Novel Substitution Pattern in Calixarene Chemistry
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https://figshare.com/articles/dataset/Dimercuration_of_Calix_4_arenes_Novel_Substitution_Pattern_in_Calixarene_Chemistry/2336530
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资源简介：
A mercuration
reaction of tetrapropoxycalix[4]arene immobilized in the cone conformation gave a mixture of two dimercurated products (meta,meta and meta,para) in approximately a 1:1 ratio. Both regioisomers represent
inherently chiral compounds, which makes them very attractive for
design of novel receptors. As demonstrated by Pd-catalyzed arylation,
the different reactivity of HgCl functions in the meta,para-disubstituted isomer opens the door for regioselective
introductions of two different functional groups to achieve a substitution
pattern so far unknown in calixarene chemistry.
创建时间：
2016-02-18
