Catalytic α‑Monoallylation of Aryl Acetonitriles
收藏Figshare2016-02-16 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Catalytic_Monoallylation_of_Aryl_Acetonitriles/2249812
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α-Cyano aldehydes undergo selective transition-metal-catalyzed monoallylation to provide α-allylated nitriles. The transformation leads to linear substitution products with palladium catalysts or branched allylated nitriles using an iridium catalyst. Facile TBD-catalyzed retro-Claisen cleavage is leveraged to attain selective monoallylation.
创建时间：
2016-02-16
