Nickel(II), Palladium(II), and Platinum(II) η<sup>3</sup>-Allyl Complexes Bearing a Bidentate Titanium(IV) Phosphinoamide Ligand: A Ti←M<sub>2</sub> Dative Bond Enhances the Electrophilicity of the π-Allyl Moiety
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
Three Ti−M2 (M2 = Ni, Pd, Pt) heterobimetallic complexes, [(η3-methallyl)M2(Ph2PNtBu)2TiCl2](OTf), were synthesized in which a TiIV←M2 interaction was suggested by crystallography and DFT calculations. The TiIV←M2 interaction enhanced electrophilicity of the η3-methallyl ligand of M2, leading to high reactivity of the η3-methallyl moiety with Et2NH compared with that of the dppp analogue.
创建时间：
2016-02-26
