Intramolecular, Pd/Cu-Co-catalyzed P–C Bond Cleavage and Addition onto an Alkyne: A Route to Benzophospholes
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https://figshare.com/articles/dataset/Intramolecular_Pd_Cu_Co_catalyzed_P_C_Bond_Cleavage_and_Addition_onto_an_Alkyne_A_Route_to_Benzophospholes/2106970
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Under Pd(II)/CuI cocatalysis, o-diarylphosphinophenylalkynes cyclize in boiling toluene via C–P bond cleavage and arylphosphination of the CC bond. This protocol provides an unprecedented atom- and step-efficient access to optoelectronically and biologically interesting benzophospholes.
创建时间:
2016-02-12



