Chiral Gold Complex-Catalyzed Hetero-Diels–Alder Reaction of Diazenes: Highly Enantioselective and General for Dienes
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https://figshare.com/articles/dataset/Chiral_Gold_Complex_Catalyzed_Hetero_Diels_Alder_Reaction_of_Diazenes_Highly_Enantioselective_and_General_for_Dienes/2437057
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资源简介:
A chiral gold(I) complex-catalyzed
highly regio- and enantioselective
azo hetero-Diels–Alder reaction has been developed. The chiral
gold(I) complex acting as a Lewis acid exhibits high efficiency in
the activation of urea-based diazene dienophiles. Moreover, this chiral
gold catalyst also rendered a cascade intramolecular enyne cycloisomerization/asymmetric
azo-HDA reaction.
创建时间:
2016-02-19



