Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes
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https://figshare.com/articles/dataset/Synthesis_and_Characterization_of_Rhodium_Complexes_with_Phosphine_Stabilized_Germylenes/2498959
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资源简介：
The reaction of phosphine-stabilized germylenes (1a,b) with dimer complex [Rh2(μ-Cl)2(COD)2] leads to the corresponding phosphine–germylene–Rh(I)
complexes (2a,b). Interestingly, the stability
of these complexes depends strongly on the nature of the substituent
of the germylene fragment. Indeed, the complex (2a) with
the chloro-germylene ligand isomerizes into a metallacycle rhodium
complex (3a) via germylene insertion into the Rh–Cl
bond, while the complex with the phenyl-substituted germylene (2b) was isolated and represents the first stable Rh(I)–germylene
complex with a Rh–Cl bond.
创建时间：
2012-08-06
