Successive C–C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed [4 + 2] Cycloaddition across the Diol, Hydroxycarbonyl, or Dione Oxidation Levels
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https://figshare.com/articles/dataset/Successive_C_C_Coupling_of_Dienes_to_Vicinally_Dioxygenated_Hydrocarbons_Ruthenium_Catalyzed_4_2_Cycloaddition_across_the_Diol_Hydroxycarbonyl_or_Dione_Oxidation_Levels/2435173
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资源简介：
The ruthenium(0) catalyst generated from Ru3(CO)12 and tricyclohexylphosphine or BIPHEP promotes successive
C–C coupling of dienes to vicinally dioxygenated hydrocarbons
across the diol, hydroxyketone, and dione oxidation levels to form
products of [4 + 2] cycloaddition. A mechanism involving diene-carbonyl
oxidative coupling followed by intramolecular carbonyl addition from
the resulting allylruthenium intermediate is postulated.
创建时间：
2016-02-19
