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Single-Crystal to Single-Crystal Transformation of Cyclic Water Heptamer to Another (H<sub>2</sub>O)<sub>7</sub> Cluster Containing Cyclic Pentamer

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NIAID Data Ecosystem2026-03-06 收录
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A discrete cyclic water heptamer trapped inside a three-dimensional coordination polymer undergoes single-crystal to single-crystal transformation to a new type of water heptamer containing a pentamer ring buttressed by a dimer, accompanied by phase transition below 273 K. The structural differences between the heptamers in BF4− and ClO4− salts have been attributed to the influence of the anions in the channels.

创建时间:
2008-05-07
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