Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates
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https://figshare.com/articles/dataset/Phosphine_Catalyzed_Vicinal_Acylcyanation_of_Alkynoates/3123424
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资源简介：
Phosphine organocatalysis enabled
vicinal acylcyanation of alkynoates
with acyl cyanides to form acrylonitrile derivatives with a tetrasubstituted
alkene moiety. The acyl and cyano groups were introduced at the α
and β carbon atoms, respectively, of the C–C triple bond
in the alkynoates with complete regioselectivity and high anti stereoselectivity. A variety of functional groups in
the acyl cyanides and alkynoates were tolerated.
创建时间：
2016-03-28
