Phosphine-Catalyzed Vicinal Acylcyanation of Alkynoates
收藏NIAID Data Ecosystem2026-03-09 收录
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Phosphine organocatalysis enabled vicinal acylcyanation of alkynoates with acyl cyanides to form acrylonitrile derivatives with a tetrasubstituted alkene moiety. The acyl and cyano groups were introduced at the α and β carbon atoms, respectively, of the C–C triple bond in the alkynoates with complete regioselectivity and high anti stereoselectivity. A variety of functional groups in the acyl cyanides and alkynoates were tolerated.
创建时间：
2016-03-28
