[Tc<sup>I</sup>(CN)<sub>3</sub>(CO)<sub>3</sub>]<sup>2-</sup> and [Re<sup>I</sup>(CN)<sub>3</sub>(CO)<sub>3</sub>]<sup>2-</sup>: Case Studies for the Binding Properties of CN<sup>-</sup> and CO
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The cyano carbonyl complexes [99Tc(CN)3(CO)3]2- and [Re(CN)3(CO)3]2- were synthesized and fully characterized. These complexes are additional members of the well-known d6 transition metal complex series [M(CN)3(CO)3]n-. The analytical data obtained in this study thus offer a unique opportunity to study similarities and differences of cyanide and carbonyl binding in transition metal complexes.
创建时间：
2004-06-28
