Probing the Group Tolerance of a Li/Cl Phosphinidenoid Complex Using Alkenyl-Substituted Aldehydes
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https://figshare.com/articles/dataset/Probing_the_Group_Tolerance_of_a_Li_Cl_Phosphinidenoid_Complex_Using_Alkenyl_Substituted_Aldehydes/2506789
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资源简介：
Reaction of the Li/Cl phosphinidenoid pentacarbonyltungsten
complex 2 (R = CH(SiMe3)2) with
unsaturated
aldehydes 3, 4, 9, 10, and 13 yielded the new oxaphosphirane complexes 5, 7, 11, 12, and 14 and thus revealed a clear preference for CO vs
CC bond addition (i) and for 1,2- vs 1,4 addition (ii). Complexes
were characterized by NMR, IR spectroscopy, and mass spectrometry
and, in the case of 14a, by single-crystal X-ray analysis.
创建时间：
2016-02-20
