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A Novel Asymmetric Hydroarsination Reaction Promoted by a Chiral Organopalladium Complex

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NIAID Data Ecosystem2026-03-06 收录
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The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-μ-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.

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2016-06-03
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