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1,4- to 1,5-Homologation of Alkene−Carbene and Alkyne−Carbene Complexes of Chromium and Tungsten: The Clue to Reactivity

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/1_4_to_1_5_Homologation_of_Alkene_Carbene_and_Alkyne_Carbene_Complexes_of_Chromium_and_Tungsten_The_Clue_to_Reactivity/3306118
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The carbene carbon of 1,4-alkene and -alkyne carbene complexes of chromium and tungsten (1 and 2) reacts with nucleophiles such as hydrides originating from dihydropyridine and methyllithium to give upon CO and alkyne (or alkene) insertions polycyclic lactones 6 and 7, cyclopentanones 10 and 11, and cyclopentanols 12.
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2005-01-03
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