1,4- to 1,5-Homologation of Alkene−Carbene and Alkyne−Carbene Complexes of Chromium and Tungsten: The Clue to Reactivity
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https://figshare.com/articles/dataset/1_4_to_1_5_Homologation_of_Alkene_Carbene_and_Alkyne_Carbene_Complexes_of_Chromium_and_Tungsten_The_Clue_to_Reactivity/3306118
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资源简介:
The carbene carbon of 1,4-alkene and -alkyne
carbene complexes of chromium and tungsten (1 and 2)
reacts with nucleophiles such as hydrides originating
from dihydropyridine and methyllithium to give upon
CO and alkyne (or alkene) insertions polycyclic lactones 6 and 7, cyclopentanones 10 and 11, and cyclopentanols 12.
创建时间:
2005-01-03



