相关数据集
Proton and Electron Additions to Iron(II) Dinitrogen Complexes Containing Pendant Amines
Protonation of an iron C–H activated complex containing pendant amines in the presence of N2 generated a cis-(H)FeII–N2 complex. Addition of acid protonates the pendant amines. Reduction of the proto
NIAID Data Ecosystem40
Equations describing the dependence of the volume on the number of atoms/residues lining individual cavities.
aIn the equation y corresponds to the volume (Å3) and x to the number of atoms (or residues); the R2 value provides the measure of fit of the power law to the data points. Fitting linear equations pro
NIAID Data Ecosystem40
Synthesis and Structures of Cadmium Carboxylate and Thiocarboxylate Compounds with a Sulfur-Rich Coordination Environment: Carboxylate Exchange Kinetics Involving Tris(2-mercapto-1‑ t ‑butylimidazolyl)hydroborato Cadmium Complexes, [Tm Bu t ]Cd(O 2 CR)
A series of cadmium carboxylate compounds in a sulfur-rich environment provided by the tris(2-tert-butylmercaptoimidazolyl)hydroborato ligand, namely, [TmBut]CdO2CR, has been synthesized via the r
NIAID Data Ecosystem10
A Nonheme Thiolate-Ligated Cobalt Superoxo Complex: Synthesis and Spectroscopic Characterization, Computational Studies, and Hydrogen Atom Abstraction Reactivity
The synthesis and characterization of a Co(II) dithiolato complex Co(Me3TACN)(S2SiMe2) (1) are reported. Reaction of 1 with O2 generates a rare thiolate-ligated cobalt–superoxo species Co(O2)(Me3
NIAID Data Ecosystem40
Copper Complexes as Bioinspired Models for Lytic Polysaccharide Monooxygenases
We report here two copper complexes as first functional models for lytic polysaccharide monooxygenases, mononuclear copper-containing enzymes involved in recalcitrant polysaccharide breakdown. These c
NIAID Data Ecosystem40
