A Stable Naked Dithiolene Radical Anion and Synergic THF Ring-Opening
收藏Figshare2020-09-26 更新2026-04-28 收录
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https://figshare.com/articles/dataset/A_Stable_Naked_Dithiolene_Radical_Anion_and_Synergic_THF_Ring-Opening/13042712
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Reaction of the lithium dithiolene radical 2• with the imidazolium salt [{(Me)CN(i-Pr)}2CH]+[Cl]− (in a 1:1 molar ratio) gives the first stable naked anionic dithiolene radical 3•, which, when coupled with hexasulfide, [{(Me)CN(i-Pr)}2CH]+2[S6]2– (4), and N-heterocyclic silylene 5, unexpectedly results in synergic THF ring-opening via a radical mechanism.
创建时间：
2020-09-26
