Direct Oxidative Coupling of Enamines and Electron-Deficient Amines: TBAI/TBHP-Mediated Synthesis of Substituted Diaminoalkenes under Metal-Free Conditions
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https://figshare.com/articles/dataset/Direct_Oxidative_Coupling_of_Enamines_and_Electron_Deficient_Amines_TBAI_TBHP_Mediated_Synthesis_of_Substituted_Diaminoalkenes_under_Metal_Free_Conditions/2244319
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资源简介:
A metal-free cross-coupling of enamines
and electron-deficient
amines through oxidative C(sp2)–N bond formation
has been realized by using TBAI as catalyst and TBHP as oxidant. This
novel strategy allows for an efficient organocatalytic synthesis of
the synthetically useful diaminoalkene derivatives and is highlighted
by appealing features such as readily available of the starting materials,
wide substrate scope and transition-metal-free characteristics.
创建时间:
2016-02-16



