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Antimony−Antimony Bond Formation by Reductive Elimination from a Hafnium Bis(stibido) Complex

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Antimony_Antimony_Bond_Formation_by_Reductive_Elimination_from_a_Hafnium_Bis_stibido_Complex/3045667
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资源简介:
The bis(stibido) complex CpCp*Hf(SbMes2)2 (2) was prepared and structurally characterized. Complex 2 reacts with 2 equiv of xylylisocyanide to give the bis-insertion product CpCp*Hf[C(SbMes2)N(2,6-MeC6H3)]2 (4). The reaction of 2 with oxidants (I2 and O2) or donors (carbon monoxide and diphenylacetylene) or thermolysis promotes the reductive elimination of Sb2Mes4.
创建时间:
2006-11-27
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