Synthetic Tuning of Electronic and Photophysical Properties of 2‑Aryl-1,3-Benzothiaphospholes
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A series of 2-aryl-1,3-benzothiaphospholes have been synthesized from 1-mercapto-2-phosphinobenzene and a variety of acid chlorides. The structure of 2-phenyl-1,3-benzothiaphosphole was established using X-ray diffraction. The electrochemical and photophysical properties of each benzothiaphosphole are reported and some of these molecules exhibit reversible 1-electron reductions.
创建时间:
2013-08-02



