Divergent Synthesis of 2‑Aminofurans via Palladium-Catalyzed Acetoxylative, Alkoxylative, and Hydroxylative Cycloisomerization of Homoallenyl Amides
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https://figshare.com/articles/dataset/Divergent_Synthesis_of_2_Aminofurans_via_Palladium_Catalyzed_Acetoxylative_Alkoxylative_and_Hydroxylative_Cycloisomerization_of_Homoallenyl_Amides/2142883
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资源简介:
A fine-tunable
transformation, including Pd-catalyzed acetoxylative,
alkoxylative, and hydroxylative cycloisomerization of homoallenyl
amides, has been realized with hypervalent iodine organic compounds
as the oxidants, giving polysubstituted 2-aminofurans in promising
yields at room temperature. The selective formation of three different
types of products from the same starting materials makes this reaction
particularly attractive and useful for organic synthesis.
创建时间:
2016-02-13



