Structural and Spectroscopic Characterization of Plutonyl(VI) Nitrate under Acidic Conditions
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The plutonyl(VI) dinitrate complex [PuO2(NO3)2(H2O)2]·H2O (1) has been structurally characterized by single-crystal X-ray diffraction and spectroscopically characterized by solid-state vis-NIR and Raman spectroscopies. Aqueous solution spectroscopic studies indicate only weak plutonyl(VI) nitrate complexation, with the mononitrate complex dominating and negligible dinitrate formation, even in concentrated nitric acid.
创建时间：
2016-02-23
