Dataset for Concave P-Stereogenic Phosphorodiamidite Ligands for Enantioselective Rh(I)-Catalysis
收藏DataCite Commons2026-05-05 更新2024-07-13 收录
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https://yareta.unige.ch/archives/c9b1a0b5-f909-4eaf-847a-6301c954b91c
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资源简介：
The development of a new class of concave P-stereogenic phosphorodiamidite ligands, derived from Tröger Bases (TBs), is explored. These ligands, characterized by their remarkable stability and unique structural geometry around the P-atom, are used in asymmetric Rh(I)-catalyzed additions of boronic acids to NH-isatins resulting in excellent reactivities and reasonable enantioselectivity (e.r. up to 92:8).
提供机构：
Université de Genève, Yareta
创建时间：
2024-03-05
