Syntheses and Structural Characterization of Mono‑, Di‑, and Tetranuclear Silver Carbone Complexes
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https://figshare.com/articles/dataset/Syntheses_and_Structural_Characterization_of_Mono_Di_and_Tetranuclear_Silver_Carbone_Complexes/3543848
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资源简介：
Mono-,
di-, and tetranuclear silver complexes 1–3 were successfully synthesized and isolated using a bis(chalcogenane)carbon(0)
(BChC)-bearing iminosulfane ligand. In these complexes, BChCs exhibit
κ2C,N and κ3C,C′,N coordination modes. The molecular structure of [Ag4(BChCs)2](TfO)4 (3) reveals the peculiar
electronic structure of BChC, which features two electron lone pairs
on the central carbon atom. Furthermore, the structure of 3 provides the first experimental proof that carbones can act as multidentate
ligands in multication clusters.
创建时间：
2016-08-16
